Tunable plasmonic lattices of silver nanocrystals

Autor: Prasert Sinsermsuksakul, Peidong Yang, Andrea R. Tao
Rok vydání: 2007
Předmět:
Zdroj: Nature Nanotechnology. 2:435-440
ISSN: 1748-3395
1748-3387
DOI: 10.1038/nnano.2007.189
Popis: Silver nanocrystals are ideal building blocks for plasmonic materials that exhibit a wide range of unique and potentially useful optical phenomena. Individual nanocrystals display distinct optical scattering spectra and can be assembled into hierarchical structures that couple strongly to external electromagnetic fields. This coupling, which is mediated by surface plasmons, depends on the shape and arrangement of the nanocrystals. Here we demonstrate the bottom-up assembly of polyhedral silver nanocrystals into macroscopic two-dimensional superlattices using the Langmuir-Blodgett technique. Our ability to control interparticle spacing, density and packing symmetry allows for tunability of the optical response over the entire visible range. This assembly strategy offers a new, practical approach to making novel plasmonic materials for application in spectroscopic sensors, subwavelength optics and integrated devices that utilize field-enhancement effects.
Databáze: OpenAIRE