Investigating the Structure Directing Properties of Designer 1,8-Naphthalimide and Amphiphilic Sulfonate Anions and Their FeIII Thiosemicarbazone Complexes

Autor:	Sarah O. Akponasa, Tony D. Keene, Aaron J. Scott, Jonathan A. Kitchen, Robert J. Laverick, Dominic J. Wales, Anthony B. Carter
Rok vydání:	2017
Předmět:	Langmuir 010405 organic chemistry Chemistry Stereochemistry General Chemistry 010402 general chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Sulfonate Amphiphile Polymer chemistry General Materials Science Long chain Semicarbazone
Zdroj:	Crystal Growth & Design. 17:5129-5144
ISSN:	1528-7505 1528-7483
Popis:	The FeIII thiosemicarbazone complexes of five organic sulfonate based anions are reported {[Fe(L1)2](X), where L1 = acetylthiazole 4-phenylthiosemicarbazone and X = N-(p-aminobenzenesulfonate)-1,8-naphthalimide (1), N-(m-aminobenzenesulfonate)-1,8-naphthalimide (2), N-(5-amino-1-naphthalenesulfonate)-1,8-naphthalimide (3), N-(5-amino-2-naphthalenesulfonate)-1,8-naphthalimide (4), and hexadecylsulfonate (5)}. Four complexes feature 1,8-naphthalimide based anions, known for their structure directing properties through π-based interactions, and one complex features a long chain sulfonate anion to introduce amphiphilicity to the complex to allow formation of Langmuir–Blodgett films. A full structural and photophysical study is reported for naphthalimide based anions 1–4 and complexes [Fe(L1)2](1–4), and a structural and Langmuir study is reported for [Fe(L1)2](5).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c64a1da33990ba7eacdc64551e94a68 https://doi.org/10.1021/acs.cgd.7b00534 Zobrazit plný text záznamu