Aromatic Hydroxylation Reactivity of a Mononuclear Cu(II)−Alkylperoxo Complex

Autor:	Joseph D. Scanlon, Junji Teraoka, Shinobu Itoh, Christopher J. Cramer, Takahiro Matsumoto, Atsushi Kunishita, Masatatsu Suzuki
Rok vydání:	2007
Předmět:	Chemistry Ligand chemistry.chemical_element General Chemistry Biochemistry Copper Medicinal chemistry Catalysis Adduct Hydroxylation chemistry.chemical_compound Colloid and Surface Chemistry Pyridine Acetone Organic chemistry Reactivity (chemistry) Triethylamine
Zdroj:	Journal of the American Chemical Society. 129:7248-7249
ISSN:	1520-5126 0002-7863
Popis:	Reaction of copper(II) complex 1X supported by the tridentate bis(pyridylmethyl)amine ligand containing m-substituted phenyl groups at the 6-positions of the pyridine rings (LX) with H2O2 in the presence of triethylamine (NEt3) in acetone generates a copper(II)−alkylperoxo species 2X [2-hydroxy-2-hydroperoxypropane (HHPP) adduct]. The alkylperoxo intermediate 2X undergoes an efficient aromatic ligand hydroxylation reaction, producing a phenolate complex 4X via another intermediate 3X. Kinetic studies on the aromatic hydroxylation process are reported together with spectral characterization of 2X.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c56a0a3ee768da40439d7fb94181a20 https://doi.org/10.1021/ja071623g Zobrazit plný text záznamu