Intermolecular Visible-Light Photoredox Atom-Transfer Radical [3+2]-Cyclization of 2-(Iodomethyl)cyclopropane-1,1-dicarboxylate with Alkenes and Alkynes

Autor:	Yue Qu, Yingming Yao, Pixu Li, Xiangyong Gu, Qi Yang, Xiang Li
Rok vydání:	2013
Předmět:	Radical Organic Chemistry Intermolecular force chemistry.chemical_element General Chemistry Photochemistry Radical cyclization Catalysis Cyclopropane chemistry.chemical_compound chemistry Cyclopentene Lewis acids and bases Iridium Cyclopentane
Zdroj:	Chemistry - A European Journal. 19:11878-11882
ISSN:	0947-6539
DOI:	10.1002/chem.201301943
Popis:	Radical chemistry! A visible-light-promoted, tin/boron-free intermolecular [3+2] atom-transfer radical cyclization reaction was developed by using iridium polyphenylpridinyl complex as the sensitizer. 2-(Iodomethyl)cyclopropane-1,1-dicarboxylate reacted with various alkenes and alkynes to form cyclopentane and cyclopentene derivatives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c009430ecb208da9fd3ab16b91cf6bb https://doi.org/10.1002/chem.201301943 Zobrazit plný text záznamu Plný text ve formátu PDF