Palladium-catalysed O -Allylation of α-Hydroxyphosphonates: An Expedient Entry into Phosphono-oxaheterocycles
| Autor: | Aurélie Dos Santos, Nicolas Fincias, Mansour Dolè Kerim, Martin Cattoen, Stellios Arseniyadis, Laurent El Kaim |
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| Přispěvatelé: | Laboratoire de synthèse organique (DCSO), École polytechnique (X)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), School of Biological and Chemical Sciences, Queen Mary University of London |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Metacyclophanes
010405 organic chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry chemistry.chemical_element General Chemistry Pudovik reaction 010402 general chemistry Metathesis 01 natural sciences 0104 chemical sciences Ring-closing metathesis chemistry Organic chemistry α-Hydroxyphosphonates O-allylation Palladium |
| Zdroj: | Advanced Synthesis and Catalysis Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 360 (3), pp.449-454. ⟨10.1002/adsc.201701150⟩ |
| ISSN: | 1615-4150 1615-4169 |
| Popis: | International audience; We report here an unprecedented palladium‐catalysed O‐allylation of α‐hydroxyphosphonates. The method was eventually included in a sequential Pudovik/Tsuji‐Trost type O‐allylation/Ring‐Closing Metathesis to afford a variety of phosphorylated heterocycles of various sizes ranging from 5 to 16 starting from readily available aldehydes. |
| Databáze: | OpenAIRE |
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