Bis(2,2′-bipyridine)(2-hydroxy-2,2-diphenylacetato)copper(II) nitrate dihydrate

Autor:	Shao-Wei Mai, Xuan Xu, Yi-Fan Luo, Chun Zheng, Xiaojun Wang
Rok vydání:	2010
Předmět:	Metal-Organic Papers Crystallography chemistry.chemical_compound Chemistry Ligand Copper(II) nitrate Pyridine Stacking General Materials Science General Chemistry Condensed Matter Physics Bioinformatics 2 2'-Bipyridine
Zdroj:	Acta Crystallographica Section E: Structure Reports
ISSN:	1600-5368
Popis:	In the title complex, [Cu(C(14)H(11)O(3))(C(10)H(8)N(2))(2)]NO(3)·2H(2)O, the Cu(II) atom is coordinated by four N atoms from two 2,2'-bipyridine ligands and two O atoms from one benzilate ligand in a distorted octa-hedral geometry. A supra-molecular network is formed via inter-molecular O-H⋯O and C-H⋯O hydrogen-bonding inter-actions. π-π stacking inter-actions between neighboring pyridine rings are also present, the centroid-centroid distance being 3.808 (2) Å.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0b9d4504390f1c86e59f989343fd003e https://doi.org/10.1107/s1600536810035555 Zobrazit plný text záznamu