Enantioselective dearomatization reactions of heteroarenes by anion-binding organocatalysis

Autor: Martin Aleksiev, Olga García Mancheño
Rok vydání: 2023
Předmět:
Zdroj: Chemical Communications. 59:3360-3372
ISSN: 1364-548X
1359-7345
Popis: The anion-binding catalysis technology has emerged as a potent alternative to metal catalysis, which together with the design of novel, tunable anion-receptor motifs, has provided new entries for the enantioselective dearomatization of heteroarenes through a chiral contact ion pair formation by activation of the electrophilic reaction partner. In this feature, we provide an overview of the different methodologies and advances in anion-binding catalyzed dearomatization reactions of different heteroarenes.
Databáze: OpenAIRE