Iodomethyl Group as a Hydroxymethyl Synthetic Equivalent: Application to the Syntheses of d -manno-Hept-2-ulose and l -Fructose Derivatives
| Autor: | Bernard Bessieres, Christophe Morin |
|---|---|
| Rok vydání: | 2003 |
| Předmět: |
Stereochemistry
Pentoses Fructose Lithium Chemical synthesis Catalysis chemistry.chemical_compound Group (periodic table) Ketoses Organic chemistry Hydroxymethyl Hydrocarbons Iodinated chemistry.chemical_classification Molecular Structure Chemistry Monosaccharides Organic Chemistry Ketose Glycoside Stereoisomerism Heptoses Aldose Reagent Indicators and Reagents Mannose Methane |
| Zdroj: | The Journal of Organic Chemistry. 68:4100-4103 |
| ISSN: | 1520-6904 0022-3263 |
| DOI: | 10.1021/jo0342166 |
| Popis: | The one-carbon elongation of aldoses to ketoses using iodomethyllithium as the key reagent in the homologation step is exemplified by the preparation of two carbohydrates of chemical and biological interests: d-manno-hept-2-ulose from d-mannose and l-fructose from l-arabinose. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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