Vapor switching of the luminescence mechanism in a Re(v ) complex
| Autor: | Kenta Sasaki, Haruka Yoshino, Yuushi Shimoda, Kiyoshi Miyata, Ryo Ohtani, Hitomi Yamate, Masaaki Ohba, Ken Onda, Hiroki Miura |
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| Rok vydání: | 2020 |
| Předmět: |
Materials science
Ligand Metals and Alloys Physics::Optics Charge (physics) General Chemistry Photochemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Color changes Materials Chemistry Ceramics and Composites Methanol Luminescence Quantum Astrophysics::Galaxy Astrophysics |
| Zdroj: | Chemical Communications. 56:12961-12964 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d0cc05462c |
| Popis: | A ReV complex demonstrates methanol selective luminescent color changes from red to green together with enhancements of the corresponding luminescence quantum yields twenty-three times. These characteristic responses are caused by the switching of the characters of the emissive states from metal-to-ligand charge transfer to d-d transition along with a single-crystal-to-single-crystal ligand exchange reaction. |
| Databáze: | OpenAIRE |
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