Cr(III), Fe(III) and Co(III) complexes of tetradentate (ONNO) Schiff base ligands: synthesis, characterization, properties and biological activity
| Autor: | Eren Keskioğlu, Fatma Hamurcu, Servet Çete, Ayla Balaban Gündüzalp, Birgül Erk |
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| Rok vydání: | 2007 |
| Předmět: |
Chromium
Magnetic Resonance Spectroscopy Spectrophotometry Infrared Stereochemistry Metal ions in aqueous solution Iron chemistry.chemical_element Microbial Sensitivity Tests Ligands Mass Spectrometry Analytical Chemistry Metal chemistry.chemical_compound Octahedral molecular geometry Polymer chemistry Molecule Instrumentation Spectroscopy Schiff Bases Schiff base Bacteria Ligand Chemistry Electric Conductivity Fungi Temperature Cobalt Atomic and Molecular Physics and Optics Piperazine visual_art Thermogravimetry visual_art.visual_art_medium |
| Zdroj: | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 70(3) |
| ISSN: | 1386-1425 |
| Popis: | A series of metal complexes were synthesized from equimolar amounts of Schiff bases: 1,4-bis[3-(2-hydroxy-1-naphthaidimine)propyl]piperazine (bappnaf) and 1,8-bis[3-(2-hydroxy-1-naphthaldimine)-p-menthane (damnaf) with metal chlorides. All of synthesized compounds were characterized by elemental analyses, spectral (UV-vis, IR, H-1-C-13 NMR, LC-MS) and thermal (TGA-DTA) methods, magnetic and conductance measurements. Schiff base complexes supposed in tetragonal geometry have the general formula [M(bappnaf or damnaf)]Cl center dot nH(2)O, where M = Cr(III), Co(III) and n = 2, 3. But also Fe(III) complexes have octahedral geometry by the coordination of two water molecules and the formula is [Fe(bappnaf or damnaf)(H2O)(2)]Cl. The changes in the selected vibration bands in FT-IR indicate that Schiff bases behave as (ONNO) tetradentate ligands and coordinate to metal ions from two phenolic oxygen atoms and two azomethine nitrogen atoms. Conductance measurements suggest 1:1 electrolytic nature of the metal complexes. The synthesized compounds except bappnaf ligand have the antimicrobial activity against the bacteria: Escherichia coli (ATCC 11230), Yersinia enterocolitica (ATCC 1501), Bacillus magaterium (RSKK 5117), Bacillus subtilis (RSKK 244), Bacillus cereus (RSKK 863) and the fungi: Candida albicans (ATCC 10239). These results have been considerably interest in piperazine derivatives due to their significant applications in antimicrobial studies. (C) 2007 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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