Phenyl-functionalized diiron propanediselenolato complexes containing intramolecular bridging diphosphine ligands
| Autor: | Guang-Ri Xu, Jing-Yan Shang, Hui-Ling Gao, Lu Liu, Chang-Gong Li |
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| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Xylene Crystal structure 010402 general chemistry 01 natural sciences Medicinal chemistry Redox 0104 chemical sciences Acetic acid chemistry.chemical_compound chemistry Ferrocene Propane Intramolecular force Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Cyclic voltammetry |
| DOI: | 10.6084/m9.figshare.5216401.v1 |
| Popis: | Reactions of [(μ-SeCH2)2CHC6H5]Fe2(CO)6 (A) with 1,1′-bis(diphenylphosphino)ferrocene (dppf) or 1,3-bis(diphenylphosphino)propane (dppp) in refluxing xylene yielded [(μ-SeCH2)2CHC6H5]Fe2(CO)4(μ-dppf) (1) or [(μ-SeCH2)2CHC6H5]Fe2(CO)4(μ-dppp) (2) in moderate yields. The chemical structures of both complexes were characterized by spectroscopic methods and X-ray crystallography, and the electronic structures were further investigated by UV–vis. The redox properties of both complexes in the absence and presence of acetic acid were observed by cyclic voltammetry (CV). |
| Databáze: | OpenAIRE |
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