Single crystal growth, optical absorption and luminescence properties under VUV-UV synchrotron excitation of type III Pr3+:KGd(PO3)4
| Autor: | Francesc Díaz, Magdalena Aguiló, Maria Cinta Pujol, Irina Adell, Matthieu Lancry, Nadège Ollier, Rosa Maria Solé |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Scintillation
Multidisciplinary Materials science lcsh:R Doping Analytical chemistry lcsh:Medicine 02 engineering and technology Scintillator 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Article 0104 chemical sciences Differential thermal analysis lcsh:Q lcsh:Science 0210 nano-technology Ground state Absorption (electromagnetic radiation) Luminescence Monoclinic crystal system |
| Zdroj: | Scientific Reports, Vol 10, Iss 1, Pp 1-15 (2020) Scientific Reports |
| ISSN: | 2045-2322 |
| DOI: | 10.1038/s41598-020-63556-w |
| Popis: | Scintillator materials are widely used for a variety of applications such as high energy physics, astrophysics and medical imaging. Since the ideal scintillator does not exist, the search for scintillators with suitable properties for each application is of great interest. Here, Pr3+-doped KGd(PO3)4 bulk single crystals with monoclinic structure (space group: P21) are grown from high temperature solutions and their structural, thermal and optical properties are studied as possible candidates for scintillation material. The change in the unit cell parameters as a function of the Pr3+ level of doping and temperature is studied. Differential thermal analysis reveals that KGd0.942Pr0.058(PO3)4 is stable until 1140 K. The 5d3, 5d2 and 5d1 levels of Pr3+ with respect to the 3H4 ground state are centred at 166, 196 and 218 nm, respectively, in this host. The luminescence of KGd0.990Pr0.010(PO3)4, by exciting these 5d levels, shows intense emissions centred at 256 and 265 nm from the 5d1 to 3F3,4 and 1G4 levels of Pr3+ with a short decay time of 6 ns. The 6P3/2,5/2,7/2 → 8S7/2 transitions of Gd3+ appear after exciting the 5d levels of Pr3+ and the 4 f levels of Gd3+, showing an energy transfer between Pr3+ and Gd3+. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|