Aquabis(3-methoxy-2-pyridonato)(2,2′:6′,2′′-terpyridine)ruthenium(II)–acetonitrile–water (1/1/1)
| Autor: | Edgar Algarín, Eric P. Kelson, Norman S. Dean |
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| Rok vydání: | 2007 |
| Předmět: |
Denticity
Pyridines Hydrogen bond Stereochemistry Ligand Molecular Conformation chemistry.chemical_element General Medicine Crystallography X-Ray Ligands Transfer hydrogenation Medicinal chemistry Catalysis General Biochemistry Genetics and Molecular Biology Ruthenium chemistry.chemical_compound chemistry Organometallic Compounds Ruthenium Compounds Hydrogenation Terpyridine Crystallization Acetonitrile Structural analog |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 63:m108-m110 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270107004246 |
| Popis: | The title compound, [Ru(C(6)H(6)NO(2))(2)(C(15)H(11)N(3))(H(2)O)] x CH(3)CNx H(2)O, is a transfer hydrogenation catalyst supported by nitrogen-donor ligands. This octahedral Ru(II) complex features rare monodentate coordination of 3-methoxy-2-pyridonate ligands and interligand S(6)S(6) hydrogen bonding. Comparison of the title complex with a structural analog with unsubstituted 2-pyridonate ligands reveals subtle differences in the orientation of the ligand planes. |
| Databáze: | OpenAIRE |
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