Electron nuclear double resonance of stable Rh centers in solution-grown NaCl single crystals

Autor:	Henk Vrielinck, Freddy Callens, M Zdravkova, Dirk Schoemaker, H Vercammen, Etienne Boesman
Rok vydání:	1997
Předmět:	Electron nuclear double resonance Crystallography Chemistry law Doping General Physics and Astronomy Halide chemistry.chemical_element Orthorhombic crystal system Electron paramagnetic resonance law.invention Rhodium
Zdroj:	Journal of applied physics
ISSN:	1089-7550 0021-8979
Popis:	Unlike the photographically important silver halides, large NaCl single crystals can be grown from solution. In such NaCl crystals, with doping comparable to practical AgCl and AgBr microcrystals, three stable Rh centers were detected and studied by electron paramagnetic resonance (EPR) and electron nuclear double resonance (ENDOR). The primary center was identified as a nonlocally compensated [RhCl6]4− complex, at variance with earlier reported EPR work. By lack of sufficient EPR and/or ENDOR evidence, the identity of the two other Rh related centers with orthorhombic and isotropic symmetry respectively, remains rather speculative.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0a7ee3b2512bd64aa41eba739c7df77e https://doi.org/10.1063/1.366059 Zobrazit plný text záznamu