Electroreductive hydrogenation of activated olefins using the concept of site isolation

Autor:	Shiho Furukawa, Marie Saito, Ryohei Tsuda, Toshiki Tajima, Shinsuke Tomida
Rok vydání:	2016
Předmět:	chemistry.chemical_classification 010405 organic chemistry Chemistry Protonation Sulfonic acid 010402 general chemistry Electrochemistry 01 natural sciences Cathode 0104 chemical sciences law.invention lcsh:Chemistry lcsh:Industrial electrochemistry lcsh:QD1-999 law Organic chemistry lcsh:TP250-261
Zdroj:	Electrochemistry Communications, Vol 73, Iss, Pp 46-49 (2016)
ISSN:	1388-2481
DOI:	10.1016/j.elecom.2016.10.015
Popis:	Electroreductive hydrogenation of activated olefins was investigated using the concept of site isolation. It was shown by electrochemical measurements as well as preparative electrolyses that the use of silica gel-supported sulfonic acid (Si-SO3H) promotes the protonation step in electroreductive hydrogenation of activated olefins without electroreductive destruction at the cathode. On the basis of the concept of site isolation, electroreductive hydrogenation of several activated olefins was successfully carried out to provide the corresponding hydrogenation products in high yields. Keywords: Site isolation, Electroreductive hydrogenation, Activated olefin, Solid-supported acid, Cation exchange
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0a68c7945db7607b3bd95be331fedc82 https://doi.org/10.1016/j.elecom.2016.10.015 Zobrazit plný text záznamu Full Text from ScienceDirect