A heterogeneous single-atom palladium catalyst surpassing homogeneous systems for Suzuki coupling
| Autor: | Javier Pérez-Ramírez, Edvin Fako, Manuel A. Ortuño, Sharon Mitchell, Zupeng Chen, Evgeniya Vorobyeva, Sean M. Collins, Sylvia Richard, Paul A. Midgley, Núria López, Gianvito Vilé |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Biomedical Engineering Bioengineering 02 engineering and technology 010402 general chemistry 01 natural sciences Catalysis Metal Catalytic mechanisms Nanoscale materials Theoretical chemistry chemistry.chemical_compound Suzuki reaction General Materials Science Electrical and Electronic Engineering Chemoselectivity Graphitic carbon nitride 021001 nanoscience & nanotechnology Condensed Matter Physics Atomic and Molecular Physics and Optics 0104 chemical sciences Chemical engineering chemistry visual_art Functional group visual_art.visual_art_medium Degradation (geology) 0210 nano-technology |
| Zdroj: | RECERCAT (Dipòsit de la Recerca de Catalunya) Recercat. Dipósit de la Recerca de Catalunya instname Nature Nanotechnology, 13 |
| ISSN: | 1748-3387 |
| Popis: | Palladium-catalysed cross-coupling reactions, central tools in fine-chemical synthesis, predominantly employ soluble metal complexes despite recognized challenges with product purification and catalyst reusability1– 3. Attempts to tether these homogeneous catalysts on insoluble carriers have been thwarted by suboptimal stability, which leads to a progressively worsening performance due to metal leaching or clustering4. The alternative application of supported Pd nanoparticles has faced limitations because of insufficient activity under the mild conditions required to avoid thermal degradation of the substrates or products. Single-atom heterogeneous catalysts lie at the frontier5–18. Here, we show that the Pd atoms anchored on exfoliated graphitic carbon nitride (Pd-ECN) capture the advantages of both worlds, as they comprise a solid catalyst that matches the high chemoselectivity and broad functional group tolerance of stateof- the-art homogeneous catalysts for Suzuki couplings, and also demonstrate a robust stability in flow. The adaptive coordination environment within the macroheterocycles of ECN facilitates each catalytic step. The findings illustrate the exciting opportunities presented by nanostructuring single atoms in solid hosts for catalytic processes that remain difficult to heterogenize. |
| Databáze: | OpenAIRE |
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