Integration of P-CuO thin sputtered layers onto microsensor platforms for gas sensing

Autor: Philippe Menini, Antoine Barnabé, Chabane Talhi, Audrey Chapelle, Frédéric Blanc, Lionel Presmanes, Imane El Younsi, Yohann Thimont, Philippe Tailhades, Corine Bonningue
Přispěvatelé: Centre National de la Recherche Scientifique - CNRS (FRANCE), Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), Centre interuniversitaire de recherche et d'ingenierie des matériaux (CIRIMAT), Centre National de la Recherche Scientifique (CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC), Équipe MICrosystèmes d'Analyse (LAAS-MICA), Laboratoire d'analyse et d'architecture des systèmes (LAAS), Université Toulouse - Jean Jaurès (UT2J)-Université Toulouse 1 Capitole (UT1), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut National des Sciences Appliquées - Toulouse (INSA Toulouse), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Toulouse - Jean Jaurès (UT2J)-Université Toulouse 1 Capitole (UT1), Université Fédérale Toulouse Midi-Pyrénées, Service Instrumentation Conception Caractérisation (LAAS-I2C), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT), Université Toulouse Capitole (UT Capitole), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut National des Sciences Appliquées - Toulouse (INSA Toulouse), Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Institut National des Sciences Appliquées (INSA)-Université Toulouse - Jean Jaurès (UT2J), Université de Toulouse (UT)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Université Toulouse Capitole (UT Capitole), Institut National Polytechnique de Toulouse - INPT (FRANCE)
Jazyk: angličtina
Rok vydání: 2017
Předmět:
Copper oxide
thin film
Analytical chemistry
02 engineering and technology
01 natural sciences
7. Clean energy
Biochemistry
[SPI.MAT]Engineering Sciences [physics]/Materials
gas sensor
Analytical Chemistry
law.invention
chemistry.chemical_compound
pulsed temperature
law
Thin film
photolithography
Instrumentation
021001 nanoscience & nanotechnology
Atomic and Molecular Physics
and Optics

Pulsed temperature
[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]
Optoelectronics
0210 nano-technology
Layer (electronics)
Photolithography
Materials science
Matériaux
Temperature cycling
RF sputtering
CuO
tenorite
metal oxide microsensor
micro-hotplate
Science des matériaux
Article
Sputtering
Nitrogen dioxide
Electrical and Electronic Engineering
business.industry
010401 analytical chemistry
Tenorite
Metal oxide microsensor
0104 chemical sciences
chemistry
Micro-hotplate
business
Gas sensor
Carbon monoxide
Zdroj: Sensors (Basel, Switzerland)
Sensors
Sensors, MDPI, 2017, 17 (6), pp.1409. ⟨10.3390/s17061409⟩
Sensors, 2017, 17 (6), pp.1409. ⟨10.3390/s17061409⟩
Sensors; Volume 17; Issue 6; Pages: 1409
ISSN: 1424-8220
DOI: 10.3390/s17061409⟩
Popis: International audience; P-type semiconducting copper oxide (CuO) thin films deposited by radio-frequency (RF) sputtering were integrated onto microsensors using classical photolithography technologies. The integration of the 50-nm-thick layer could be successfully carried out using the lift-off process. The microsensors were tested with variable thermal sequences under carbon monoxide (CO), ammonia (NH3), acetaldehyde (C2H4O), and nitrogen dioxide (NO2) which are among the main pollutant gases measured by metal-oxide (MOS) gas sensors for air quality control systems in automotive cabins. Because the microheaters were designed on a membrane, it was then possible to generate very rapid temperature variations (from room temperature to 550 °C in only 50 ms) and a rapid temperature cycling mode could be applied. This measurement mode allowed a significant improvement of the sensor response under 2 and 5 ppm of acetaldehyde.
Databáze: OpenAIRE