A physicochemical investigation of ionic liquid mixtures
| Autor: | Colin R. Crick, Tom Welton, Patricia A. Hunt, Matthew T. Clough, Heiko Niedermeyer, Oliver P. Whitaker, John Gräsvik |
|---|---|
| Přispěvatelé: | Commission of the European Communities |
| Rok vydání: | 2014 |
| Předmět: |
Chemistry
Multidisciplinary Mixing (process engineering) Ab initio THERMAL-PROPERTIES Thermodynamics COMMON ION SALTS Conductivity Ion Quantitative Biology::Cell Behavior VAPORIZATION ENTHALPIES chemistry.chemical_compound Viscosity RAMAN ANION TEMPERATURES Phase (matter) Physics::Atomic and Molecular Clusters Organic chemistry AB-INITIO Science & Technology SOLVATOCHROMIC COMPARISON METHOD General Chemistry BINARY-MIXTURES Chemistry chemistry Physical Sciences Ionic liquid Glass transition |
| Zdroj: | Chemical Science |
| ISSN: | 2041-6520 |
| Popis: | A comprehensive study of ionic liquid mixtures reveals a remarkable adhesion to ideal mixing laws, with some consistent exceptions. Ionic liquids have earned the reputation of being ‘designer solvents’ due to the wide range of accessible properties and the degree of fine-tuning afforded by varying the constituent ions. Mixtures of ionic liquids offer the opportunity for further fine-tuning of properties. A broad selection of common ionic liquid cations and anions are employed to create a sample of binary and reciprocal binary ionic liquid mixtures, which are analysed and described in this paper. Physical properties such as the conductivity, viscosity, density and phase behaviour (glass transition temperatures) are examined. In addition, thermal stabilities of the mixtures are evaluated. The physical properties examined for these formulations are found to generally adhere remarkably closely to ideal mixing laws, with a few consistent exceptions, allowing for the facile prediction and control of properties of ionic liquid mixtures. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|