Total Synthesis of (±)-Kainic Acid: A Photochemical C–H Carbamoylation Approach
| Autor: | Takuma Kamon, Tetsuaki Tanaka, Yayoi Irifune, Takehiko Yoshimitsu |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
Kainic acid
Kainic Acid Molecular Structure Chemistry Stereochemistry Alkaloid Organic Chemistry Total synthesis Marine Biology Stereoisomerism Photochemistry Biochemistry Indole Alkaloids chemistry.chemical_compound Molecule Organic chemistry heterocyclic compounds Proline Physical and Theoretical Chemistry Derivative (chemistry) |
| Zdroj: | Organic Letters. 13:2674-2677 |
| ISSN: | 1523-7052 1523-7060 |
| Popis: | A novel photochemical C-H carbamoylation of an octahydroisoindole derivative with PhNCO has allowed the authors to provide a unique access to a highly functionalized proline motif from which total synthesis of (±)-kainic acid, a bioactive marine alkaloid, has been accomplished. |
| Databáze: | OpenAIRE |
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