Crystal structure of bromido-nitro-syl-bis(tri-phenyl-phosphane-κP)nickel(II)
| Autor: | Sarantos Marinakis, Rose Hockley, Hira Irshad, Tippu S. Sheriff, Majid Motevalli |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
crystal structure
Stereochemistry chemistry.chemical_element Crystal structure C—H⋯π interactions Crystal chemistry.chemical_compound C—H...π interactions Bromide triphenylphosphane ligand General Materials Science Coordination geometry Crystallography Chemistry Hydrogen bond triphenylphosphane ligand nickel complex General Chemistry Condensed Matter Physics Data Reports Nickel QD901-999 nitrosyl complex hydrogen bonds Nitro |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 4, Pp m87-m88 (2015) |
| ISSN: | 2056-9890 |
| Popis: | The asymmetric unit of the title complex, [NiBr(NO){P(C6H5)3}2], comprises two independent molecules each with a similar configuration. The NiIIcation is coordinated by one bromide anion, one nitrosyl anion and two triphenylphosphane molecules in a distorted BrNP2tetrahedral coordination geometry. The coordination of the nitrosyl group is non-linear, the Ni—N—O angles being 150.2 (5) and 151.2 (5)° in the two independent molecules. In the crystal, molecules are linked by weak C—H...Br hydrogen bonds and weak C—H...π interactions into a three-dimensional supramolecular architecture. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|