Direct Triple Annulations: A Way to Design Large Triazastarphenes with Intertwined Hexagonal Packing

Autor:	Qian Li, Chady Moussallem, Frédéric Castet, Luca Muccioli, Marie-Anne Dourges, Thierry Toupance, Yohann Nicolas
Přispěvatelé:	Li, Qian, Moussallem, Chady, Castet, Frédéric, Muccioli, Luca, Dourges, Marie-Anne, Toupance, Thierry, Nicolas, Yohann
Rok vydání:	2021
Předmět:	Organic Chemistry organi semiconductors charge transport DFT Physical and Theoretical Chemistry Biochemistry
Zdroj:	Organic Letters. 24:344-348
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.1c04001
Popis:	A new straightforward synthetic strategy has been elaborated to achieve star-shaped triazatrinaphthylene and, for the first time, triazatrianthrylene derivatives. Their solution- and solid-state properties were thoroughly characterized by cyclic voltammetry, UV-vis absorption spectroscopy, X-ray diffraction, and density functional theory calculations. Original hexagonal molecular arrangements were found in the crystal phase, which opens a new pathway for designing materials with improved three-dimensional charge-transport properties.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::091b973596ad743d8f5403493db5f0de https://doi.org/10.1021/acs.orglett.1c04001 Zobrazit plný text záznamu