Effect of Medium Capacity on the Relationship between Chemical Heterogeneity and Linearly Adsorbed Solute Dispersion into Fixed Beds
Autor: | K. Kaabeche-Djerafi, N. Bendjaballah-Lalaoui, S. Semra |
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Jazyk: | angličtina |
Rok vydání: | 2011 |
Předmět: | |
DOI: | 10.5281/zenodo.1083725 |
Popis: | The paper aims at investigating influence of medium capacity on linear adsorbed solute dispersion into chemically heterogeneous fixed beds. A discrete chemical heterogeneity distribution is considered in the one-dimensional advectivedispersive equation. The partial differential equation is solved using finite volumes method based on the Adam-Bashforth algorithm. Increased dispersion is estimated by comparing breakthrough curves second order moments and keeping identical hydrodynamic properties. As a result, dispersion increase due to chemical heterogeneity depends on the column size and surprisingly on the solid capacity. The more intense capacity is, the more important solute dispersion is. Medium length which is known to favour this effect vanishing according to the linear adsorption in fixed bed seems to create nonmonotonous variation of dispersion because of the heterogeneity. This nonmonotonous behaviour is also favoured by high capacities. {"references":["S. Semra, M. Sardin, and M. O. Simonnot, \"Effect of Chemical\nHeterogeneity on Adsorbed Solute Dispersion at Column Scale\", AIChE\nJ., vol. 54, no 4, pp 950-956, 2008.","S. Semra, M. Sardin, and M. O. Simonnot. \"A New Mixing-Cell-in-\nSeries Model to Predict Breakthrough Curve in Chemically\nHeterogeneous Media at Column Scale\", Chemical Product and Process\nModeling, vol. 4 Iss. 1, Art. 31, 2009.","M. Sardin, \"Modélisation du transport transitoire de solutés en milieux\nporeux : Les modèles linéaires\", 1993, Sciences Géologiques, Bulletin\nN┬░ 46, pp 197-216.","C. Zheng and G. D. Bennett. \"Applied contaminant transport modeling :\nTheory and practice\". USA : Van Nostrand Reinhold, 1995, 440 p.","M. SRADIN et al. \"Modeling the nonequilibrium transport of linearly\ninteracting solutes in porous media : A Review\". Water Resources\nResearch, vol. 27, no 9, pp 2287-2307, 1991.","J. Villermaux. \"Génie de la réaction chimique : Conception et\nfonctionnement des réacteurs\". Paris, France : TEC & DOCLAVOISIER,\n1993, 448 p.","A. Bisio, R. L. Kabel, \"Scaleup of chemical processes : Conversion from\nlaboratory scale tests to successful commercial size design\", John Wiley\n& Sons, Inc., New York, U.S.A, 1985.","S. Pivovarov, \"Dispersion of compounds in transport processes:\nVelocity dispersion model\", J. of Colloid and Interface Science, vol.\n289, pp 600-603, 2005.","M. Sahimi. \"Flow and transport in porous media and fractured rock:\nFrom classical methods to modern approaches\". Germany : VCH\nVerlagsgesellschaft mbH, 1995, 482 p."]} |
Databáze: | OpenAIRE |
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