Determination of the Molecular and Structural Characteristics of Okenia, Mango, and Banana Starches

Autor: Imad A. Farhat, Millan-Testa Ce, Luis A. Bello-Pérez, M.G.C. Méndez-Montealvo, Marie-Astrid Ottenhof
Rok vydání: 2005
Předmět:
Zdroj: Journal of Agricultural and Food Chemistry. 53:495-501
ISSN: 1520-5118
0021-8561
DOI: 10.1021/jf048862x
Popis: Starches were isolated from nonconventional sources (banana, mango, and okenia) and their characteristics were examined using polarized light microscopy, X-ray diffraction pattern, Fourier transform infrared (FTIR) spectroscopy, and differential scanning calorimetry (DSC). Banana starch granules were of an ellipsoidal shape with size between approximately 8 and 20 microm; okenia had the smallest granule size, between approximately 2 and 5 microm. The three starches showed the Maltese cross, indicative of an intact granule structure. Okenia and mango starches had the A-type X-ray diffraction pattern, common to native cereal starches, whereas banana starch showed a mixture between A- and B-type pattern. Banana starch had the highest temperature (77.6 degrees C) and enthalpy (23.4 J/g) of gelatinization in excess water conditions; okenia had the lowest temperature (71.2 degrees C) and enthalpy (15 J/g), which may be related to the X-ray diffraction pattern and its small granule size. Both the okenia and mango starches had a higher molar mass and gyration radius than banana starch, which may be related to the differences determined in their crystalline structures.
Databáze: OpenAIRE