Metal-free and metallo-porphyrazines with eight [5-thiopentyl 2-methoxy-4,6-bis (trifluoromethyl) benzoate] substituent
| Autor: | Ergün Gonca |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Trifluoromethyl
Polymers and Plastics Pyrazine 010405 organic chemistry Substituent General Chemistry Fluorine-19 NMR Porphyrazine 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences chemistry.chemical_compound chemistry Pyridine Materials Chemistry Ceramics and Composites Organic chemistry Solubility Benzoic acid |
| DOI: | 10.6084/m9.figshare.5229778.v1 |
| Popis: | The reaction of (5-hydroxypentylthio magnesium porphyrazine) with 2-methoxy-4,6-bis(trifluoromethyl)benzoic acid in DCCI and PTSA, esterified MgPz having [5-thiopentyl 2-methoxy-4,6-bis(trifluoromethyl)benzoate] substituent was obtained. Further reactions of the metal-free porphyrazine with M2+(Mg, Co, Cu, Zn, Fe) acetates have produced the metallo-porphyrazines. Finally, by the reaction of FePzCl with pyridine or pyrazine compounds, [FePz(py)2] and [FePz(pyz)]n complexes were prepared as the novel stable complexes, respectively. The target compounds have been characterized by using different spectroscopic methods such as FT-IR, UV-Vis, mass, 1H, 13C, and 19F NMR together with elemental analysis. The aggregation and the solubility features were indicated in various concentrations and solvents. |
| Databáze: | OpenAIRE |
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