Peracetic Acid: An Atom-Economical Reagent for Pd-Catalyzed Acetoxylation of C–H Bonds

Autor:	Christopher J. Mulligan, Jeremy S. Parker, King Kuok (Mimi) Hii, Oliver J. Newton, Sharanappa M. Bagale
Přispěvatelé:	Engineering and Physical Sciences Research Council
Rok vydání:	2018
Předmět:	Technology Engineering Chemical ARYLATION ANILIDES Chemistry Multidisciplinary General Chemical Engineering chemistry.chemical_element Acetoxylation of C-H bonds FUNCTIONALIZATIONS 02 engineering and technology OXIDATION 010402 general chemistry 01 natural sciences Medicinal chemistry ACETANILIDES Catalysis ACTIVATION chemistry.chemical_compound Engineering Atom economy Peracetic acid Environmental Chemistry Green & Sustainable Science & Technology Acetanilide Science & Technology Renewable Energy Sustainability and the Environment food and beverages Atom (order theory) General Chemistry MILD 021001 nanoscience & nanotechnology 0104 chemical sciences Chemistry chemistry Reagent Physical Sciences Science & Technology - Other Topics 0210 nano-technology Palladium
Zdroj:	ACS Sustainable Chemistry & Engineering. 7:1611-1615
ISSN:	2168-0485
DOI:	10.1021/acssuschemeng.8b05370
Popis:	Peracetic acid can be used universally as a source of acetate and an oxidant for the selective acetoxylation of C–H bonds in compounds containing ortho-directing groups, catalyzed by Pd(OAc)2. Compared to previous procedures, where persulfates and PhI(OAc)2 were used, the new protocol provides significant improvements in atom efficiency, product yield, substrate scope, cost, scalability, and environmental impact.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::08c7c95b789af64922c967c0f00fabbe https://doi.org/10.1021/acssuschemeng.8b05370 Zobrazit plný text záznamu