Spectral characteristic and crystal-field calculations for new Er(III) phosphor of the type [Er(SP)4](-) (where SP=C6H5S(O)(2)NP(O)(OCH3)(2)(-))
| Autor: | Paula Gawryszewska, Marcin Sobczyk, G. Boulon, Janina Legendziewicz, V.M. Amirkhanov, V.A. Trush, Kamil Korzeniowski, Wieslaw Strek, Malgorzata Guzik, Yannick Guyot |
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| Přispěvatelé: | Institut Lumière Matière [Villeurbanne] (ILM), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Lanthanide
Biophysics Analytical chemistry chemistry.chemical_element Phosphor 02 engineering and technology Crystal structure 010402 general chemistry 01 natural sciences Biochemistry Crystal Erbium [SPI]Engineering Sciences [physics] [CHIM]Chemical Sciences Isostructural Spectroscopy ComputingMilieux_MISCELLANEOUS [PHYS]Physics [physics] Chemistry General Chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Atomic and Molecular Physics and Optics 0104 chemical sciences Physical chemistry 0210 nano-technology Monoclinic crystal system |
| Zdroj: | Journal of Luminescence Journal of Luminescence, Elsevier, 2016, 169, Polish Acad Sci, Inst Low Temp \& Struct Res. ⟨10.1016/j.jlumin.2015.03.029⟩ |
| ISSN: | 0022-2313 1872-7883 |
| DOI: | 10.1016/j.jlumin.2015.03.029⟩ |
| Popis: | The studies of lanthanide β-diketones and their derivatives have been greatly intensified because of their potential use in photonic devices. In this work the results of spectroscopic properties of a new erbium phosphor are presented. Optical characteristics of the title chelate was based on absorption and emission spectroscopy. The crystal-field calculation using phenomenological model was performed basing on Stark components from absorption and emission low temperature spectra. The CF and CCF parameters for Nd(III) (D. Kulesza, M. Sobczyk, J. Legendziewicz, O.M. Moroz, V.M. Amirkhanov, Struct. Chem., 21 (2010) 425) have been applied as starting points in the fitting procedures for [Er(SP)4]−. Na[Er(SP)4] and Na[Nd(SP)4] are isostructural and crystallize in the monoclinic system (space group P21/c). The crystal lattice consists of two independent polymeric chains with the same kind of coordination of Er and Na ions. |
| Databáze: | OpenAIRE |
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