The structures and properties of zinc(II) and cadmium(II) coordination polymers based on semi-rigid phenylenediacetate and 1,4-bis(2-methylimidazol-1-ylmethyl)benzene linkers
| Autor: | Mürsel Arıcı, Andrew D. Burrows, Güneş Günay Sezer, Okan Zafer Yeşilel, Daniel Rixson, Hakan Erer |
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| Rok vydání: | 2019 |
| Předmět: |
Denticity
Coordination polymer chemistry.chemical_element 02 engineering and technology Zinc 010402 general chemistry 01 natural sciences Inorganic Chemistry chemistry.chemical_compound Materials Chemistry Thermal stability Cadmium(II) complexes Physical and Theoretical Chemistry Benzene 4-bis(2-methylimidazol-1-ylmethyl)benzene complexes Cadmium 021001 nanoscience & nanotechnology Condensed Matter Physics Phenylenediacetate complexes 0104 chemical sciences Electronic Optical and Magnetic Materials Crystallography chemistry Polycatenane Ceramics and Composites Zinc(II) complexes 0210 nano-technology Luminescence |
| Zdroj: | JOURNAL OF SOLID STATE CHEMISTRY Sezer, G G, Arıcı, M, Rixson, D, Burrows, A D, Yeşilel, O Z & Erer, H 2019, ' The structures and properties of zinc(II) and cadmium(II) coordination polymers based on semi-rigid phenylenediacetate and 1,4-bis(2-methylimidazol-1-ylmethyl)benzene linkers ', Journal of Solid State Chemistry, vol. 269, pp. 246-256 . https://doi.org/10.1016/j.jssc.2018.09.017 |
| DOI: | 10.1016/j.jssc.2018.09.017 |
| Popis: | A systematic investigation into the reactions of o- and p-phenylenediacetic acid with zinc(II) and cadmium(II) salts in the presence of the semi-rigid 1,4-bis(2-methylimidazol-1-ylmethyl)benzene (pbmeix) co-ligand is reported. Five new coordination polymers – [Zn(μ-opda)(μ-pbmeix)0.5]n 1, {[Zn(μ-ppda)(μ-pbmeix)]·H2O}n 2, {[Zn(μ-ppda)(μ-pbmeix)]∙0.5pbmeix·H2O}n 3, {[Cd(μ-opda)(μ-pbmeix)]·0.5DMF}n 4 and [Cd(μ-ppda)(μ-pbmeix)0.5]n 5 (o/ppda = 1,2-/1,4-phenylenediacetate) – have been prepared and structurally characterised. Compounds 1 and 5 were found to form three-dimensional coordination networks, 2 forms a two-dimensional structure whereas both 3 and 4 form one-dimensional nanotubular structures. Compounds 1 and 4 are opda complexes in which the dicarboxylate shows a tridentate coordination mode in 1 and a tetradentate coordination mode in 4. Compounds 2, 3 and 5 are ppda complexes in which the dicarboxylate adopts bidentate (2, 3) and hexadentate (5) coordination modes. The structure of 2 contains interpenetrated 2D frameworks and is a polycatenane with ppda linkers from one framework passing through Zn2(μ-pbmeix)2 rings from a neighbouring framework. The thermal stability of complexes 1–4 and luminescence properties of complexes 1 and 4 are also reported. |
| Databáze: | OpenAIRE |
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