Bis(tetra-n-butylammonium) di-μ-chloro-bis[(tetramethyl buta-1,3-diene-1,2,3,4-tetracarboxylato-κ2C1,C4)palladium]

Autor:	Eduardo Pérez, Jorge Vives, Gregorio Sánchez, José Luis Monereo Pérez, Luis F. García, José Luis Serrano
Rok vydání:	2002
Předmět:	Stereochemistry Chemistry General Medicine Crystal structure Metallacycle Bite angle Medicinal chemistry General Biochemistry Genetics and Molecular Biology Metal Molecular geometry visual_art visual_art.visual_art_medium Moiety Molecule Chelation
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 58:m404-m406
ISSN:	0108-2701
Popis:	The anionic complex in the title compound, (C(16)H(36)N)(2)[Pd(2)(C(12)H(12)O(8))(2)Cl(2)], lies on a centre of inversion, so that the [Pd(2)(mu-Cl)(2)] core is planar, which is the most frequent conformation found for complexes containing this moiety in the Cambridge Structural Database [October 2001 Release; AllenKennard (1993). Chem. Des. Autom. News, 8, 1, 31-37]. This dinuclear complex has a Pd...Pd distance of 3.5119 (4) A. The bite angle of the chelating ligand [79.79 (8) degrees] distorts the square-planar coordination around the metal atom.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::07ce6d13f0e5d8f5c528cc5c1d5edc1e https://doi.org/10.1107/s0108270102009642 Zobrazit plný text záznamu Plný text