catena-Poly[[bis(quinolin-8-amine-κ2N,N′)cadmium(II)]-μ-cyanido-κ2N:C-[dicyanidonickel(II)]-μ-cyanido-κ2C:N]
| Autor: | Fatima Setifi, Selma Khelfa, Zouaoui Setifi, Christopher Glidewell, Marwa Touil, Mohammed Hadi Al-Douh |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
crystal structure
Denticity Crystallography synthesis 010405 organic chemistry Hydrogen bond Chemistry Coordination polymer Stacking Crystal structure 010402 general chemistry hydrogen bonding 01 natural sciences 0104 chemical sciences chemistry.chemical_compound coordination polymer Group (periodic table) QD901-999 Atom |
| Zdroj: | IUCrData, Vol 6, Iss 6, p x210568 (2021) |
| ISSN: | 2414-3146 |
| Popis: | In the title compound, [CdNi(C9H8N2)2(CN)4] n , the Cd and Ni atoms both lie on centres of inversion in space group P21/c. The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of two cyano ligands, while the square planar Ni atom is coordinated by the C atoms of four cyano ligands. These units form a one-dimensional coordination polymer containing an (–NC—Ni—CN—Cd–) n backbone, and the coordination polymer chains are linked into a three-dimensional array by a combination of N—H...N and C—H...N hydrogen bonds, augmented by a π–π stacking interaction. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|