| Autor: |
Sousa Amadeu, Nader de, Grünberg, Bob, Frydel, Jarek, Werner, Mayke, Limbach, Hans-Heinrich, Breitzke, Hergen, Buntkowsky, Gerd |
| Rok vydání: |
2021 |
| DOI: |
10.26083/tuprints-00019687 |
| Popis: |
The ²H-NMR solid echo spectra of biphenyl molecules as guests in the mesopores of neat and silylated SBA-15 have been measured as a function of temperature. At low temperatures typical ²H-Pake patterns with parameters of (Qzz = 132 kHz, corresponding to Qcc = 176 kHz) and (η = 0.04) are observed. All samples exhibit a strong reduction of the melting point from the bulk value of 342.4 K to values between 222 K and 229 K, depending on both the pore diameter and the surface state and a glass like behavior of the biphenyl molecules in the melting regime. Employing the Roessler two-phase model of the modeling of glass-transitions by ²H-solid state NMR the distribution of activation energies for the rotational motions has been determined. At temperatures closely below the glass-transition temperature deviations from a static Pake pattern of an aromatic deuteron are observed, which indicate a pre-melting motion of biphenyl, which could be caused by C₂-ring flips of the phenyl rings. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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