Synthesis and Characterization of Molecularly Imprinted Polymers for Phenoxyacetic Acids
| Autor: | Tao Song, Huiting Zhang, Canping Pan, Tiechun Chen, Fulin Zong |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: |
Molecular model
molecularly imprinted polymers 2-methylphenoxyacetic acid (2-MPA) phenoxyacetic herbicides molecular modeling MCPA Full Research Paper Catalysis lcsh:Chemistry Inorganic Chemistry chemistry.chemical_compound Molecule Organic chemistry Physical and Theoretical Chemistry lcsh:QH301-705.5 Molecular Biology Spectroscopy Chemistry Organic Chemistry Molecularly imprinted polymer General Medicine Computer Science Applications Phenoxyacetic acid Characterization (materials science) Functional monomer lcsh:Biology (General) lcsh:QD1-999 |
| Zdroj: | International Journal of Molecular Sciences; Volume 9; Issue 1; Pages: 98-106 International Journal of Molecular Sciences, Vol 9, Iss 1, Pp 98-106 (2008) International Journal of Molecular Sciences |
| ISSN: | 1422-0067 |
| DOI: | 10.3390/ijms9010098 |
| Popis: | 2-methylphenoxyacetic acid (2-MPA), 2-methyl-4-chlorophenxyacetic acid (MCPA) and 4-chlorophenoxyacetic acid (4-CPA) were imprinted to investigate the cross-selectivities of molecularly imprinted polymers (MIPs). The result indicates that 2-MPA, which is similar in shape, size and functionality with phenoxyacetic herbicides, are suitable to be used as a suitable template to prepare the MIPs for retaining phenoxyacetic herbicides. To study the ion-pair interactions between template molecules and functional monomer 4-vinylpiridine (4-VP), computational molecular modeling was employed. The data indicate that the cross-selectivities of MIPs for phenoxyacetic acid herbicides depend on the binding energies of complexes. |
| Databáze: | OpenAIRE |
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