Aromatization and desulphurisation of liquefied petroleum gas over Zn-containing zeolite catalysts modified by transition metals

Autor:	Nurgaliyev Nurzhan Nurlybekovich, Bagasharova Bates Muhtarovna, Shapovalova Larissa Borisovna, Tuktin Balga Tuktievich, Tenizbayeva Aliya Serikovna
Rok vydání:	2018
Předmět:	Reaction conditions General Energy Transition metal Chemistry Yield (chemistry) Composition (visual arts) Raw material Zeolite Liquefied petroleum gas Nuclear chemistry Catalysis
Zdroj:	International Journal of Oil, Gas and Coal Technology. 1:1
ISSN:	1753-3317 1753-3309
DOI:	10.1504/ijogct.2018.10019021
Popis:	In this paper, treatment of liquefied petroleum gas (LPG) over Zn-containing zeolite catalysts modified by Mn, Cu and Fe was studied. The authors investigated catalytic activity in the aromatisation and desulphurisation reactions of propane-propylene and propane-butane fractions (PPF and PBF respectively). It was found that the feedstock composition did not actually affect conversion at elevated temperatures (550–600°C); however, yield of the resulting aromatic hydrocarbons was higher when using PPF. The activity of catalysts mainly depended on the structure and state of active sites and reaction conditions. During PPF desulphurisation, the Zn-Mn-ZSM-Al2O3 catalyst was the most active, while the Zn-Fe-ZSM-Al2O3 catalyst showed the highest activity with the PBF. Physical and chemical characteristics of the obtained catalysts were studied using various methods. [Received: September 20, 2017; Accepted: March 16, 2018]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::07428a75b0f7d57b431bb58c4201c29a https://doi.org/10.1504/ijogct.2018.10019021 Zobrazit plný text záznamu