Crystal structure of 2,3-dimethoxy-N-(4-nitrophenyl)benzamide
Autor: | Sukriye Cakmak, Zainab M. Almarhoon, Halil Kutuk, Necmi Dege, Güngör Meral, Mavişe Yaman |
---|---|
Přispěvatelé: | OMÜ |
Rok vydání: | 2018 |
Předmět: |
crystal structure
benzamide Stacking Crystal structure Dihedral angle methylacetamide 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Research Communications Crystal chemistry.chemical_compound nitrophenyl General Materials Science Benzene Benzamide nitrophenyl Crystallography dimethoxybenzene Hydrogen bond Hirshfeld surface methylacetamide General Chemistry Condensed Matter Physics 0104 chemical sciences dimethoxybenzene chemistry QD901-999 Nitro |
Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 74, Iss 1, Pp 41-44 (2018) Acta Crystallographica Section E: Crystallographic Communications |
ISSN: | 2056-9890 |
DOI: | 10.1107/s2056989017017741 |
Popis: | In the crystal, intermolecular weak C—H⋯O hydrogen bonds link the molecules into the supramolecular chains propagating along the a axis. In the title compound, C15H14N2O5, the benzene rings are nearly coplanar, making a dihedral angle of 4.89 (8)°. An intramolecular N—H⋯O hydrogen bond occurs between the imino and methoxy groups. In the crystal, weak C—H⋯O hydrogen bonds link the molecules into supramolecular chains propagating along the a-axis direction. π–π stacking is observed between parallel benzene rings of neighbouring chains, the centroid-to-centroid distance being 3.6491 (10) Å. Three-dimensional Hirshfeld surface analyses and two-dimensional fingerprint plots have been used to analyse the intermolecular interactions present in the crystal. |
Databáze: | OpenAIRE |
Externí odkaz: |