Development of highly efficient Friedel-Crafts alkylations with alcohols using heterogeneous catalysts under continuous-flow conditions
| Autor: | Nagatoshi Koumura, Yukiko Okamoto, Shū Kobayashi, Shun-ya Onozawa, Koichiro Masuda |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
inorganic chemicals
Materials science 010405 organic chemistry Continuous operation Continuous flow General Chemical Engineering General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound Montmorillonite chemistry Chemical engineering Friedel–Crafts reaction |
| Zdroj: | RSC advances. 11(39) |
| ISSN: | 2046-2069 |
| Popis: | The development of Friedel–Crafts alkylations with alcohols under continuous-flow conditions using heterogeneous catalysts is reported. The reactivities and durabilities of the examined catalysts were systematically investigated, which showed that montmorillonite clay is the best catalyst for these reactions. A high turnover frequency of 9.0 × 102 h−1 was recorded under continuous-flow conditions, and the continuous operation was successfully maintained over one week. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|