Solvent-free methylthiomethyllithium [LiCH2SMe]∞: solid state structure and thermal decomposition
| Autor: | Hans-Wolfram Lerner, Robert E. Dinnebier, Ingeborg Sänger, Stefan W. Tönnes, Kai Ruth, Edith Alig, Matthias Wagner |
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| Rok vydání: | 2005 |
| Předmět: |
Hot Temperature
Solvent free Molecular Structure Chemistry Thermal decomposition Metals and Alloys Solid-state General Chemistry Solid state structure Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Lithium Compounds Organometallic Compounds Solvents Materials Chemistry Ceramics and Composites Molecule Physical chemistry Layer (electronics) Argon atmosphere Group 2 organometallic chemistry |
| Zdroj: | Chemical Communications. :3442 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/b505096k |
| Popis: | Solvent-free [LiCH2SMe]infinity forms a layer structure consisting of four- (Li2C2), five- (Li2CS2), and six-membered (Li2C2S2) rings in the solid state; the compound violently explodes upon heating to T=160+/-5 degrees C under an argon atmosphere. |
| Databáze: | OpenAIRE |
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