Bi‐Microporous Metal–Organic Frameworks with Cubane [M4(OH)4] (M=Ni, Co) Clusters and Pore‐Space Partition for Electrocatalytic Methanol Oxidation Reaction
| Autor: | Ya-Pan Wu, Xianhui Bu, Lu-Fang Ma, Ya-Qian Lan, Jun Zhao, Jun-Wu Tian, Dongsheng Li, Shan Liu, Bo Li |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Materials science
010405 organic chemistry chemistry.chemical_element General Medicine General Chemistry Microporous material 010402 general chemistry Electrocatalyst 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Cubane Physical chemistry Metal-organic framework Isostructural Cobalt BET theory |
| Zdroj: | Angewandte Chemie International Edition. 58:12185-12189 |
| ISSN: | 1521-3773 1433-7851 |
| Popis: | Embedding cubane [M4 (OH)4 ] (M=Ni, Co) clusters within the matrix of metal-organic frameworks (MOFs) is a strategy to develop materials with unprecedented synergistic properties. Herein, a new material type based on the pore-space partition of the cubic primitive minimal-surface net (MOF-14-type) has been realized. CTGU-15 made from the [Ni4 (OH)4 ] cluster not only has very high BET surface area (3537 m2 g-1 ), but also exhibits bi-microporous features with well-defined micropores at 0.86 nm and 1.51 nm. Furthermore, CTGU-15 is stable even under high pH (0.1 m KOH), making it well suited for methanol oxidation in basic medium. The optimal hybrid catalyst KB&CTGU-15 (1:2) made from ketjen black (KB) and CTGU-15 exhibits an outstanding performance with a high mass specific peak current of 527 mA mg-1 and excellent peak current density (29.8 mA cm-2 ) at low potential (0.6 V). The isostructural cobalt structure (CTGU-16) has also been synthesized, further expanding the application potential of this material type. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text