The Valence Band Structure of the [Ni(Salen)] Complex: An Ultraviolet, Soft X-ray and Resonant Photoemission Spectroscopy Study
| Autor: | Petr M. Korusenko, Alexandra V. Koroleva, Anatoliy A. Vereshchagin, Danil V. Sivkov, Olga V. Petrova, Oleg V. Levin, Alexander S. Vinogradov |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: |
Photons
Photoelectron Spectroscopy X-Rays Organic Chemistry General Medicine Ethylenediamines [Ni(Salen)] complex (NiO2N2C16H14) NiN2O2 coordination center valence band photoemission (VB PE) spectra soft X-ray and ultraviolet photoemission spectroscopy X-ray resonant photoemission spectroscopy (ResPES) participator and spectator Auger decay processes Catalysis Computer Science Applications Radiography Inorganic Chemistry Physical and Theoretical Chemistry Molecular Biology Spectroscopy |
| Zdroj: | International Journal of Molecular Sciences; Volume 23; Issue 11; Pages: 6207 |
| ISSN: | 1422-0067 |
| DOI: | 10.3390/ijms23116207 |
| Popis: | The valence band photoemission (VB PE) spectra of the [Ni(Salen)] molecular complex were measured by ultraviolet, soft X-ray and resonant photoemission (ResPE) using photons with energies ranging from 21.2 eV to 860 eV. It was found that the Ni 3d atomic orbitals’ (AOs) contributions are most significant for molecular orbitals (MOs), which are responsible for the low-energy PE band at a binding energy of 3.8 eV in the VB PE spectra. In turn, the PE bands in the binding energies range of 8–16 eV are due to the photoionization of the MOs of the [Ni(Salen)] complex with dominant contributions from C 2p AOs. A detailed consideration was made for the ResPE spectra obtained using photons with absorption resonance energies in the Ni 2p3/2, N 1s, and O 1s Near-Edge X-ray Absorption Fine Structure (NEXAFS) spectra. A strong increase in the intensity of the PE band ab was found when using photons with an energy 854.4 eV in the Ni 2p3/2 NEXAFS spectrum. This finding is due to the high probability of the participator-Auger decay of the Ni 2p3/2−13d9 excitation and confirms the relationship between the PE band ab with the Ni 3d-derived MOs. |
| Databáze: | OpenAIRE |
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