HREELS characterization of surfaces and interfaces in self-assembled molecular monolayers
| Autor: | Ph Lang, N Kitakatsu, Francis Garnier, R Michalitsch, M. Rei Vilar, Y Bouali, Pierre Dubot |
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| Přispěvatelé: | Institut de Chimie et des Matériaux Paris-Est (ICMPE), Institut de Chimie du CNRS (INC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 1998 |
| Předmět: |
Silicon
Annealing (metallurgy) chemistry.chemical_element High resolution electron energy loss spectroscopy 02 engineering and technology 01 natural sciences chemistry.chemical_compound 0103 physical sciences Monolayer Materials Chemistry Organic chemistry ComputingMilieux_MISCELLANEOUS [PHYS]Physics [physics] 010304 chemical physics Metals and Alloys Self-assembled monolayer Surfaces and Interfaces 021001 nanoscience & nanotechnology Silane Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Chemical physics Siloxane 0210 nano-technology Platinum |
| Zdroj: | Thin Solid Films Thin Solid Films, Elsevier, 1998, 327-329, pp.236-240. ⟨10.1016/S0040-6090(98)00636-1⟩ |
| ISSN: | 0040-6090 |
| DOI: | 10.1016/s0040-6090(98)00636-1 |
| Popis: | High resolution electron energy loss spectroscopy ( HREELS ) is used to characterize the extreme surface composition and the interfaces of silane and thiol monolayers deposed on silicon and platinum crystals, respectively. Energy losses due to impact interactions are very sensitive to the molecular groups present in the extreme surface of the film. Long range dipole interactions can supply information about buried interfacial bonds. Silicon substrates were characterized before and after molecular interactions. Energy losses assigned to interfacial siloxane bonds clearly vary with previous substrate annealing. Spectra of adsorbed thiols are dominated by losses corresponding to functional groups attached to the chain-end. An energy loss at 360 cm−1 was identified as corresponding to an interfacial S–Pt bond. |
| Databáze: | OpenAIRE |
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