Synthesis of alpha,alpha'-linked oligophospholes and polyphospholes by using Pd-CuI-promoted Stille-type coupling

Autor:	Arihiro Saito, Hiroshi Imahori, Yoshihiro Matano
Rok vydání:	2010
Předmět:	Coupling (electronics) chemistry.chemical_compound Narrow band chemistry Organic Chemistry Polymer chemistry Polythiophene Alpha (ethology) Physical and Theoretical Chemistry Biochemistry Stille reaction
Zdroj:	Organic letters. 12(11)
ISSN:	1523-7052
Popis:	Palladium-copper-promoted Stille-type cross-coupling reactions between alpha-stannylphospholes and alpha-iodophospholes afforded alpha,alpha'-linked oligophospholes and polyphosphole efficiently. It has been revealed that the polyphosphole P-oxide possesses an extremely narrow band gap and a high electron-accepting ability as compared to polythiophene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::05a9b0391f7180f2000438efc291da36 https://pubmed.ncbi.nlm.nih.gov/20438105 Zobrazit plný text záznamu