Air/water interface study of cyclopentane-containing archaeal bipolar lipid analogues
| Autor: | Véronique Vié, Julie Barbeau, Loïc Lemiègre, Thierry Benvegnu, Alicia Jacquemet |
|---|---|
| Přispěvatelé: | Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Institut de Physique de Rennes (IPR), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Centre National de la Recherche Scientifique (CNRS), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Université de Rennes (UR)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: |
Air water interface
Stereochemistry Bent molecular geometry Cyclopentanes 010402 general chemistry Ring (chemistry) 01 natural sciences Biochemistry chemistry.chemical_compound Cyclopentane Molecular Biology 010405 organic chemistry Chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Air Organic Chemistry Phospholipid Ethers Water Cell Biology Lipids Archaea 0104 chemical sciences Crystallography Oxygen atom Diether lipid Polar Mannose Tetraether lipid Air/water interface |
| Zdroj: | Chemistry and Physics of Lipids Chemistry and Physics of Lipids, Elsevier, 2010, 163 (8), pp.794-9. ⟨10.1016/j.chemphyslip.2010.09.005⟩ Chemistry and Physics of Lipids, 2010, 163 (8), pp.794-9. ⟨10.1016/j.chemphyslip.2010.09.005⟩ |
| ISSN: | 0009-3084 |
| DOI: | 10.1016/j.chemphyslip.2010.09.005⟩ |
| Popis: | International audience; The synthesis of novel archaeal lipid analogues is described. The hydrophobic core of these tetraether bipolar lipids were based on a disubstituted 1,3-cyclopentane unit which was further equipped with mannosyl polar head groups. This hemimacrocylcic tetraether structure that can be compared to rare archaeal lipids permit to establish the behavior of such bipolar lipid at the air/water interface. The two oxygen atoms and the cyclopentane ring were found to be of importance on this behavior. Indeed, the air/water interface comparative study of tetraether- and diether-type lipids led to conclusions on a bent conformation of the tetraether at the air/water interface in the presence of a cyclopentane unit even if the presence of the two oxygen atoms favored an opened bent shape at the beginning of the compression. |
| Databáze: | OpenAIRE |
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