Projectile Impact Shock-Induced Deformation of One-Component Polymer Nanocomposite Thin Films
| Autor: | Jinho Hyon, Manny Gonzales, Richard A. Vaia, Lawrence F. Drummy, Olawale Lawal, Yang Jiao, Omri Fried, Jason K. Streit, Edwin L. Thomas |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
Polymer nanocomposite Projectile General Engineering General Physics and Astronomy 02 engineering and technology Plasticity 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Shock (mechanics) General Materials Science Deformation (engineering) Thin film Composite material 0210 nano-technology Absorption (electromagnetic radiation) Adiabatic process |
| Zdroj: | ACS Nano. 15:2439-2446 |
| ISSN: | 1936-086X 1936-0851 |
| DOI: | 10.1021/acsnano.0c06146 |
| Popis: | Matrix-free assemblies of polymer-grafted nanoparticles (PGNs) enable mechanically robust materials for a variety of structural, electronic, and optical applications. Recent quasi-static mechanical studies have identified the key parameters that enhance canopy entanglement and promote plasticity of the PGNs below Tg. Here we experimentally explore the high-strain-rate shock impact behavior of polystyrene grafted NPs and compare their energy absorption capabilities to that of homopolystyrene for film thicknesses ranging from 75 to 550 nm and for impact velocities from 350 to 800 m/s. Modeling reveals that the initial shock compression results in a rapid temperature increase at the impact site. The uniformity of this heating is consistent with observations of greater kinetic energy absorption per mass (Ep*) of thinner films due to extensive visco-plastic deformation of molten film around the penetration site. Adiabatic heating is insufficient to raise the temperature at the exit surface of the thickest films resulting in increased strain localization at the impact periphery with less melt elongation. The extent and distribution of entanglements also influence Ep*. Structurally, each NP acts as a giant cross-link node, coupling surrounding nodes via the number of canopy chains per NP and the nature and number of entanglements between canopies anchored to different NPs. Load sharing via this dual network, along with geometrical factors such as film thickness, lead to extreme Ep* arising from the sequence of instantaneous adiabatic shock heating followed by visco-plastic drawing of the film by the projectile. These observations elucidate the critical factors necessary to create robust polymer-nanocomposite multifunctional films. |
| Databáze: | OpenAIRE |
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