Molecular interaction study through experimental and theoretical volumetric, transport and refractive properties of N-ethylaniline with aryl and alkyl ethers at several temperatures
| Autor: | Zubin R. Master, Zuber S. Vaid, Utkarsh U. More, Naved I. Malek |
|---|---|
| Rok vydání: | 2022 |
| Předmět: |
chemistry.chemical_classification
Aryl Thermodynamics Ether 02 engineering and technology Atmospheric temperature range 010402 general chemistry Condensed Matter Physics Anisole 01 natural sciences 0104 chemical sciences Electronic Optical and Magnetic Materials chemistry.chemical_compound Viscosity 020401 chemical engineering chemistry Materials Chemistry Molecule 0204 chemical engineering Physical and Theoretical Chemistry Refractive index Alkyl |
| DOI: | 10.6084/m9.figshare.1569116 |
| Popis: | To investigate the molecular interaction study between secondary amine with aryl and alkyl ether, we report densities, speeds of sound, viscosities and refractive indices of N-ethylaniline (NEA) with aryl (anisole, phenetole) and alkyl (tert-butyl methyl ether) ether over the entire composition regime and in the temperature range of 293.15–323.15 K at 5 K intervals. Various excess and transport properties were derived from the experimental data and the excess parameters were fitted to the Redlich–Kister polynomial equation using multiparametric non-linear regression analysis to derive the binary coefficients and to estimate the standard deviation. Molecular interactions between the unlike molecules were analysed through dipole–dipole interactions, cross-association between the components of the mixtures and H-bond formation. Viscosity and refractive index of the mixtures were predicted through several empirical equations and compared with the experimental results. Prigogine–Flory–Patterson statistical theory was used to predict the excess molar volume results. |
| Databáze: | OpenAIRE |
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