Inhibitory and Cooperative Effects Regulated by pH in Host–Guest Complexation between Cationic Pillar[5]arene and Reactive 2-Carboxyphthalanilic Acid

Autor:	Vanessa Nascimento, Eduardo H. Wanderlind, Ricardo F. Affeldt, Faruk Nome, Gustavo Amadeu Micke, Luis García-Río, Eduardo V. Silveira
Rok vydání:	2019
Předmět:	010405 organic chemistry Chemistry Host (biology) Organic Chemistry Pillar Cationic polymerization macromolecular substances 010402 general chemistry Inhibitory postsynaptic potential 01 natural sciences Combinatorial chemistry 0104 chemical sciences
Zdroj:	The Journal of Organic Chemistry. 84:9684-9692
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.9b01377
Popis:	The study of host-guest complexation between reactive 2-carboxyphthalanilic acid (CPA) and two cationic pillararenes has been carried out. Host-guest complexation with significant kinetic effects was observed only with the smaller cavity size pillararene (P5A). Kinetics in the pH range 1.50-6.40, ESI-MS
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::05114b8957a279c9427a5d8c3ef69fc7 https://doi.org/10.1021/acs.joc.9b01377 Zobrazit plný text záznamu