Strapped calix[4]pyrrole as a lithium salts selective receptor through separated ion-pair binding
| Autor: | Moon Gun Choi, Kyeong Im Hong, Hyeongcheol Kim, Younghun Kim, Woo Dong Jang |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Chemistry Metals and Alloys Salt (chemistry) chemistry.chemical_element General Chemistry Ion pairs Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Polymer chemistry Materials Chemistry Ceramics and Composites Proton NMR Lithium Receptor Pyrrole |
| Zdroj: | Chemical Communications. 56:10541-10544 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d0cc04809g |
| Popis: | A triazole-bearing strapped calix[4]pyrrole (1) was synthesized as a lithium salt selective ion pair receptor. 1H NMR spectral studies and X-ray crystallography showed that the capture of LiCl by 1 occurs via separated ion pair binding. Furthermore, lithium salts extracted by 1 could be solidified in the form of Li2CO3 through CO2 or K2CO3 treatment. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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