Electropolymerization of an N-Heterocyclic Carbene−Gold(I) Complex

Autor:	Christopher W. Bielawski, Alan H. Cowley, Adam B. Powell
Rok vydání:	2009
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Colloid and Surface Chemistry Monomer chemistry Polymer chemistry General Chemistry Polymer Electrochemistry Spectroscopy Biochemistry Carbene Catalysis
Zdroj:	Journal of the American Chemical Society. 131:18232-18233
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja908969q
Popis:	We report the first example of a polymer in which each monomer contains an N-heterocyclic carbene (NHC) orthogonally connected to its main chain. A polymerizable imidazolylidene-AuCl complex containing pendant bithiophene moieties was prepared in a high-yield multistep procedure. Oxidative electropolymerization of this monomer afforded the desired polymer, (Au[NHC]Cl)(n), which was characterized via electrochemical studies as well as X-ray photoelectron and UV-vis spectroscopy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0463ce8280d0d0f3e14b5bbd6a6f5c4d https://doi.org/10.1021/ja908969q Zobrazit plný text záznamu