Influence of Temperature and Electrolyte Concentration on the Structure and Catalytic Oxygen Evolution Activity of Nickel-Iron Layered Double Hydroxide
| Autor: | Edgar Ventosa, Justus Masa, Stefan Barwe, Patrick Wilde, Wolfgang Schuhmann, Yen-Ting Chen, Sabine Seisel, Corina Andronescu |
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| Rok vydání: | 2018 |
| Předmět: |
Electrolysis
Organic Chemistry Oxygen evolution chemistry.chemical_element 02 engineering and technology General Chemistry Electrolyte 010402 general chemistry 021001 nanoscience & nanotechnology Electrocatalyst 01 natural sciences Catalysis 0104 chemical sciences law.invention chemistry.chemical_compound Nickel Chemical engineering chemistry law Water splitting Hydroxide 0210 nano-technology |
| Zdroj: | Chemistry (Weinheim an der Bergstrasse, Germany). 24(52) |
| ISSN: | 1521-3765 |
| Popis: | NiFe layered double hydroxide (LDH) is inarguably the most active contemporary catalyst for the oxygen evolution reaction under alkaline conditions. However, the ability to sustain unattenuated performance under challenging industrial conditions entailing high corrosivity of the electrolyte (≈30 wt. % KOH), high temperature (>80 °C) and high current densities (>500 mA cm-2 ) is the ultimate criterion for practical viability. This work evaluates the chemical and structural stability of NiFe LDH at conditions akin to practical electrolysis, in 30 % KOH at 80 °C, however, without electrochemical polarization, and the resulting impact on the OER performance of the catalyst. Post-analysis of the catalyst by means of XRD, TEM, FT-IR, and Raman spectroscopy after its immersion into 7.5 m KOH at 80 °C for 60 h revealed a transformation of the structure from NiFe LDH to a mixture of crystalline β-Ni(OH)2 and discrete predominantly amorphous FeOOH containing minor non-homogeneously distributed crystalline domains. These structural and compositional changes led to a drastic loss of the OER activity. It is therefore recommended to study catalyst stability at industrially relevant conditions. |
| Databáze: | OpenAIRE |
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