Preparation of Ternary Platinum(II) Complexes with N-(.OMEGA.-Phenylalkyl)-1,2-ethanediamine and 2,2'-Dipyridine and the Effect of the Methylene Chain Length of the N-(.OMEGA.-Phenylalkyl)-1,2-ethanediamine in the Complexes on Intermolecular Interactions with Various Arylsulfonates
| Autor: | Masafumi Goto, Hiromasa Kurosaki, Masamitsu Sumimoto, Hiromasa Mori, Katsutoshi Tanaka |
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| Rok vydání: | 2003 |
| Předmět: |
Magnetic Resonance Spectroscopy
Molecular Structure Organoplatinum Compounds Stereochemistry Aryl Stacking chemistry.chemical_element General Chemistry General Medicine Ethylenediamines Ligands Medicinal chemistry Hydrocarbons chemistry.chemical_compound 2 2'-Dipyridyl chemistry Intramolecular force Diamine Drug Discovery Phenyl group Arylsulfonates Methylene Platinum Ternary operation Methane |
| Zdroj: | Chemical and Pharmaceutical Bulletin. 51:649-653 |
| ISSN: | 1347-5223 0009-2363 |
| Popis: | A series of ternary complexes comprised of platinum(II), 2,2'-dipyridine, and N-(omega-phenylalkyl)-1,2-ethanediamine was prepared by varying the number (n) of methylene chain carbons between the phenyl group and one of the amino groups of 1,2-ethanediamine. NMR measurements indicated that intramolecular stacking occurred for n=1 and intermolecular stacking occurred for n=3 for several of the aryl sulfonates. |
| Databáze: | OpenAIRE |
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