Dibora[10]annulenes: Construction, Properties, and Their Ring-Opening Reactions
| Autor: | Zhijun Wang, Guoping Li, Bingjie Zhang, Gang He, Demei Yu, Ni Yan, Letian Xu, Weidong Zhang, Eric Rivard |
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| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Chemistry Sensing applications Organic Chemistry Annulene 010402 general chemistry Ring (chemistry) Electrochemistry 01 natural sciences Biochemistry 0104 chemical sciences chemistry.chemical_compound Computational chemistry Pyridine Lewis acids and bases Physical and Theoretical Chemistry |
| Zdroj: | Organic Letters. 21:109-113 |
| ISSN: | 1523-7052 1523-7060 |
| Popis: | The selective construction of various dibora[10]annulenes through mild boron-tin exchange reactions is reported. Dibora[10]annulenes exhibit optical and electrochemical properties of value for future sensing applications. Controlled addition of the Lewis base pyridine to dibora[10]annulenes instigates a selective ring-opening reaction. This work explores a new area of boron chemistry that represents the first step in the potential formation of dibora[10]annulene-derived polymers. |
| Databáze: | OpenAIRE |
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