Determination of Step Free Energies from Island Shape Fluctuations on Metal Surfaces

Autor: Laurens K. Verheij, Dietmar C. Schlößer, Georg Rosenfeld, George Comsa
Přispěvatelé: Physics of Interfaces and Nanomaterials
Rok vydání: 1999
Předmět:
Zdroj: Physical review letters 82, 3843-3846 (1999). doi:10.1103/PhysRevLett.82.3843
Physical review letters, 82(19), 3843-3846. American Physical Society
ISSN: 1079-7114
0031-9007
Popis: The absolute measurement of free energies associated with crystal steps on a metal surface has been a long-standing problem. We report a reliable estimate of the step free energy on a Cu(111) crystal surface, based on an analysis of island shape fluctuations directly imaged by scanning tunneling microscopy. The result of 0.22 eV per atomic distance for steps running into close-packed directions is in good agreement with theoretical predictions.
Databáze: OpenAIRE