Adsorption of Phosphorus Oxyanions at the FeOOH(goethite)/Water Interface: The Importance of Basicity
| Autor: | Weichen Liao, Alan T. Stone, Ruizhe Xu |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Minerals
Goethite Phosphorus Inorganic chemistry chemistry.chemical_element Water Context (language use) Oxyanion General Chemistry Hydrogen-Ion Concentration Diprotic acid Phosphate Acid dissociation constant chemistry.chemical_compound Adsorption chemistry visual_art visual_art.visual_art_medium Environmental Chemistry Iron Compounds |
| Zdroj: | Environmental sciencetechnology. 55(21) |
| ISSN: | 1520-5851 |
| Popis: | PIII-containing H-phosphonate (HPO32-) and its monoethyl ester (fosetyl), essential pesticides for control of oomycete and fungal pathogens, are among the few pesticides transported by both xylem and phloem, making application as folia spray, soil spray, and trunk injection equally effective. To understand bioavailability and efficacy within soils, knowledge of adsorption to soil minerals is important. FeOOH(goethite) is often selected as an archetypal mineral surface. In the present work, H-phosphonate (with pKa values of 1.5 and 6.78) adsorption onto FeOOH is nearly complete below pH 6 and decreases to negligible amounts by pH 11, following an S-shaped curve. Fosetyl (pKa: 0.9), in contrast, does not adsorb to any significant extent, regardless of pH. To place these observations in context, adsorption of six other phosphorus oxyanions was investigated, and fitted using a CD-MUSIC model. Phosphate defines a similar S-shaped curve but adsorbs more strongly than H-phosphonate. Despite moderate differences in basicity, pH dependence and extents of adsorption for the four additional diprotic oxyanions methylphosphonate (pKas: 2.40, 8.00), benzylphosphonate (2.24, 7.93), phenylphosphonate (1.9, 7.47), and phenyl phosphate (1.1, 6.28) are quite similar to those of H-phosphonate. As with fosetyl, the other low pKa monoprotic oxyanion in our study, phenylphosphinate (pKa: 1.75), does not adsorb. Basicity, that is, pKa, is revealed to be the principal determinant of extents of adsorption. |
| Databáze: | OpenAIRE |
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